Ammonia recovery from anaerobic-fermentation liquid digestate with vacuum membrane distillation

Vacuum Membrane Distillation (VMD) is systematically investigated herein, for recovering ammonia after phosphates precipitation, towards development of a sustainable process to valorize anaerobic-fermentation liquid-digestates (separated from the sludge). Initially, batch tests were performed, with representative synthetic solutions, to identify a narrow range of conditions favoring optimal ammonia (i.e. total ammonia nitrogen-TAN) separation, mainly regarding selectivity and recovery in H2SO4 scrubbing-solution. Next, guided by the preceding test-results, targeted batch experiments with digestate samples from an industrial plant, led to determination of near-optimum conditions for ammonia recovery. Specifically, for the small TAN concentration (<200 mg/L) encountered in the digestate feeds, VMD at modest temperature (T< ~45 ◦C) and driving force Δp (<20 mbar) allowed high ammonia removal fraction r (greater than 0.85) with fair selectivity. Under such conditions, the (ammonia-water) distillate flux J exhibited linear dependence on Δp; moreover, J and pH of feed solution remained practically constant for a significant distillate removal-fraction R (under constant Δp and T). Based on theoretically supported correlation of ammonia removal-fraction r with distillate removal-fraction R, and other results, an approach is proposed for realistic preliminary design of a continuous VMD-based process, thus facilitating further steps towards large-scale process development.

https://doi.org/10.1016/j.seppur.2023.123602

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Call Stack
#	Time	Memory	Function	Location
1	1.1953	27877888	shutdown_action_hook( )	...\load.php:0
2	1.1953	27877888	do_action( $hook_name = 'shutdown' )	...\load.php:1124
3	1.1953	27878264	WP_Hook->do_action( $args = [0 => ''] )	...\plugin.php:517
4	1.1953	27878264	WP_Hook->apply_filters( $value = '', $args = [0 => ''] )	...\class-wp-hook.php:332
5	1.1953	27879424	wp_ob_end_flush_all( '' )	...\class-wp-hook.php:308
6	1.1953	27879424	ob_end_flush( )	...\functions.php:5279
7	1.1953	27977760	autoptimizeMain->end_buffering( $content = '<!doctype html>\r\n<html lang="en-US">\r\n<head>\r\n\t<meta charset="UTF-8">\r\n\t<meta name="viewport" content="width=device-width, initial-scale=1.0">\r\n\t<meta http-equiv="X-UA-Compatible" content="IE=edge">\r\n\t<link rel="profile" href="https://gmpg.org/xfn/11">\r\n\t<meta name=\'robots\' content=\'index, follow, max-image-preview:large, max-snippet:-1, max-video-preview:-1\' />\n<link rel="alternate" hreflang="en" href="https://nrre.cperi.certh.gr/ammonia-recovery-from-anaerobic-fermentation-liquid-d', 9 )	...\functions.php:5279
8	1.1959	27980728	autoptimizeScripts->read( $options = ['aggregate' => 'on', 'defer_not_aggregate' => 1, 'defer_inline' => 1, 'justhead' => '', 'forcehead' => '', 'trycatch' => '', 'js_exclude' => 'wp-includes/js/dist/, wp-includes/js/tinymce/, js/jquery/jquery.js', 'cdn_url' => '', 'include_inline' => '', 'minify_excluded' => 'on'] )	...\autoptimizeMain.php:591
9	1.1960	27980728	apply_filters( $hook_name = 'autoptimize_filter_js_dontmove', $value = [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after'] )	...\autoptimizeScripts.php:286
10	1.1960	27981136	WP_Hook->apply_filters( $value = [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after'], $args = [0 => [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after']] )	...\plugin.php:205

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Call Stack

Time

Memory

Function

Location

1.1953

27877888

shutdown_action_hook( )

...\load.php:0

1.1953

27877888

do_action( $hook_name = 'shutdown' )

...\load.php:1124

1.1953

27878264

WP_Hook->do_action( $args = [0 => ''] )

...\plugin.php:517

1.1953

27878264

WP_Hook->apply_filters( $value = '', $args = [0 => ''] )

...\class-wp-hook.php:332

1.1953

27879424

wp_ob_end_flush_all( '' )

...\class-wp-hook.php:308

1.1953

27879424

ob_end_flush( )

...\functions.php:5279

1.1953

27977760

autoptimizeMain->end_buffering( $content = '<!doctype html>\r\n<html lang="en-US">\r\n<head>\r\n\t<meta charset="UTF-8">\r\n\t<meta name="viewport" content="width=device-width, initial-scale=1.0">\r\n\t<meta http-equiv="X-UA-Compatible" content="IE=edge">\r\n\t<link rel="profile" href="https://gmpg.org/xfn/11">\r\n\t<meta name=\'robots\' content=\'index, follow, max-image-preview:large, max-snippet:-1, max-video-preview:-1\' />\n<link rel="alternate" hreflang="en" href="https://nrre.cperi.certh.gr/ammonia-recovery-from-anaerobic-fermentation-liquid-d', 9 )

...\functions.php:5279

1.1959

27980728

autoptimizeScripts->read( $options = ['aggregate' => 'on', 'defer_not_aggregate' => 1, 'defer_inline' => 1, 'justhead' => '', 'forcehead' => '', 'trycatch' => '', 'js_exclude' => 'wp-includes/js/dist/, wp-includes/js/tinymce/, js/jquery/jquery.js', 'cdn_url' => '', 'include_inline' => '', 'minify_excluded' => 'on'] )

...\autoptimizeMain.php:591

1.1960

27980728

apply_filters( $hook_name = 'autoptimize_filter_js_dontmove', $value = [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after'] )

...\autoptimizeScripts.php:286

1.1960

27981136

WP_Hook->apply_filters( $value = [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after'], $args = [0 => [0 => 'document.write', 1 => 'html5.js', 2 => 'show_ads.js', 3 => 'google_ad', 4 => 'histats.com/js', 5 => 'statcounter.com/counter/counter.js', 6 => 'ws.amazon.com/widgets', 7 => 'media.fastclick.net', 8 => '/ads/', 9 => 'comment-form-quicktags/quicktags.php', 10 => 'edToolbar', 11 => 'intensedebate.com', 12 => 'scripts.chitika.net/', 13 => '_gaq.push', 14 => 'jotform.com/', 15 => 'admin-bar.min.js', 16 => 'GoogleAnalyticsObject', 17 => 'plupload.full.min.js', 18 => 'syntaxhighlighter', 19 => 'adsbygoogle', 20 => 'gist.github.com', 21 => '_stq', 22 => 'nonce', 23 => 'post_id', 24 => 'data-noptimize', 25 => 'data-cfasync', 26 => 'data-pagespeed-no-defer', 27 => 'logHuman', 28 => 'amp-mobile-version-switcher', 29 => 'data-rocketlazyloadscript', 30 => 'rocket-browser-checker-js-after']] )

...\plugin.php:205